Gas chromatography and mass spectrometry of sphingolipid bases. Characterization of sphinga-4, 14-dienine from plasma sphingomyelin
AJ Polito, T Akita, CC Sweeley - Biochemistry, 1968 - ACS Publications
AJ Polito, T Akita, CC Sweeley
Biochemistry, 1968•ACS PublicationsAlan J. Polito. t Tadashi Akita, f and Charles C. Sweeleyf abstract: A partially purified sample
of sphinga-4, 14-dienine was obtained by chromatographic procedures from acid-catalyzed
methanolysates of human plasma sphingomyelin. The structure of this sphingolipid base
was deduced from mass spectrometric data before and after osmium tetroxide oxidation, and
by mass spectro-metric identification of sebacic acid after permanga-nate-periodate
oxidation of the base. Hexadecasphing-
of sphinga-4, 14-dienine was obtained by chromatographic procedures from acid-catalyzed
methanolysates of human plasma sphingomyelin. The structure of this sphingolipid base
was deduced from mass spectrometric data before and after osmium tetroxide oxidation, and
by mass spectro-metric identification of sebacic acid after permanga-nate-periodate
oxidation of the base. Hexadecasphing-
Alan J. Polito. t Tadashi Akita, f and Charles C. Sweeleyf abstract: A partially purified sample of sphinga-4, 14-dienine was obtained by chromatographic procedures from acid-catalyzed methanolysates of human plasma sphingomyelin. The structure of this sphingolipid base was deduced from mass spectrometric data before and after osmium tetroxide oxidation, and by mass spectro-metric identification of sebacic acid after permanga-nate-periodate oxidation of the base. Hexadecasphing-
ACS Publications